• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to a method and apparatus for producing cellulosic webs formed directly from lyocell spinning solution, and more particularly for washing the directly formed cellulosic nonwovens.
    公开号:AT519489A1
    申请号:T490/2016
    申请日:2016-10-21
    公开日:2018-07-15
    发明作者:
    申请人:Chemiefaser Lenzing Ag；
    IPC主号:
    专利说明:

    Summary
    This invention relates to a method and an apparatus for producing cellulosic nonwovens which are formed directly from Lyocell spinning solution, and in particular for washing the directly formed cellulosic nonwovens.
    1/32
    Lenzing AG, PL0591
    Method and device for forming directly formed cellulose webs
    This invention relates to a method and an apparatus for producing cellulosic nonwovens which are formed directly from Lyocell spinning solution, and in particular for washing directly formed cellulosic nonwovens.
    State of the art
    Lyocell technology is the direct dissolution of cellulose pulp or other cellulose-based raw materials in a polar
    Solvents (e.g., N-methylmorpholine-N-oxide, hereinafter referred to as' amine oxide 'or ’AO') to produce a viscous, highly shear thinning solution that can be used to form a range of useful cellulosic materials. The technology is being used commercially to create a family of staple cellulose fibers (im
    Trading under the TENCEL® brand by Lenzing AG from Lenzing in
    Austria available) which are widely used in the textile and nonwovens industry. Other cellulose products from Lyocell technology, for example filaments, foils, shells, beads & sponges, have also been disclosed.
    Cellulose staple fibers have long been used as a component for processing into nonwoven webs. However, adapting Lyocell technology to produce nonwoven webs directly would open up properties, performance potential and markets that are currently available
    Cellulose nonwoven products are not possible. This could be seen as the cellulosic equivalent of the meltblown and spunbond technologies that are widely used in the synthetic fiber industry, although due to significant technical differences it is not possible to directly adapt synthetic polymer technology for Lyocell.
    Extensive research has been carried out to invent novel technologies for forming cellulose nonwovens directly from lyocell solutions (including WO 98/26122, WO 99/47733, WO 98/07911, US
    2/32
    Lenzing AG, PL0591
    6,197,230, WO 99/64649, WO 05/106085, EP 1 358 369, EP 2 013 390). For the purposes of the present invention, the term lyocell meltblowing process encompasses both meltblown and spunbonding processes, which can result in essentially endless filaments, fibers of discrete length or mixtures of endless filaments and fibers of discrete length being obtained. The methods disclosed in the above documents are characterized in that extruded filaments from the cellulose solution in NMMO are captured by a gas stream that flows in a generally parallel direction to the path of the filaments. The cellulose solution, which is expelled through the openings, is formed into liquid strands or latent filaments, which are drawn by means of the gas flow (or considerably reduced in diameter and considerably lengthened and possibly split into several sub-filaments). The partial coagulation latent
    Filaments through wash liquor prior to web formation are also disclosed. The filaments are then formed into a fleece and processed further as required.
    task
    Previous disclosures of Lyocell meltblowing technology were primarily concerned with providing inventive solutions to the essential technical challenges of first filament formation from Lyocell spinning solution. However, any success in this area will necessitate further developments for subsequent ones
    Process steps, for example when washing. Washing Lyocell filaments is an important process step in which the solvent must be removed from the threads of thermoplastic cellulose and solvent in a controlled manner (before, during and after the formation of the fleece) in order to start developing the fiber structure and properties and cellulose / Prepare water filaments for further processing or finishing / drying. Filaments are first laid down to form a fleece during the washing step. Successful washing of directly formed cellulose fleece requires the fulfillment of a unique combination of very demanding requirements:
    3/32
    Lenzing AG, PL0591 • Rules for the degree of union and change in diameter of first-formed filaments before and during the first fleece formation. • Minimize potential damage to weak / delicate interlaced filaments in the first-formed fleece and on the
    Structure of the fleece • Regulated fleet exchange to enable fiber structure development • Minimize the consumption of water (or other washing fluids), in accordance with environmental aspects of the technology and around
    Minimize solvent recovery costs • Minimize the total investment costs for plants and buildings as well as the energy costs for washing
    There is no prior art of all of the above
    Requirements fulfilled. While papermaking technology is capable of achieving line speeds in excess of 1500 m / min, it is not applicable because sheets of paper are far more robust than the nonwovens of this invention and there is no need to wash out solvents in papermaking and the filament structure during manufacture change. Continuous filament cellulose yarn technology enables that
    Operation at high line speeds. However, the filament washing teaching applies only to very small yarns and cannot be applied to the large nonwovens of the present invention.
    description
    The disadvantages of the prior art have been solved by a new washing technology, which comprises a method and a device as disclosed here, and which enables the potential which is opened up by the direct formation of cellulose-based nonwovens from Lyocell solutions, to use entirely. Figure 1 shows a view of the invention. Those skilled in the art will recognize that other arrangements are possible.
    4/32 • ·
    Lenzing AG, PL0591
    Accordingly, a first embodiment of the invention set forth herein is a process for making cellulosic nonwovens that are formed directly from lyocell spinning solution comprising:
    • An extrusion step which uses an extrusion device (1) which is able and also capable of extruding several threads of Lyocell solution, which are arranged in particular in one or more rows to form a curtain to stretch the solution threads, in particular according to the general meltblowing principle, as described for example in EP 1093536B1.
    • A first washing step, which is carried out in a first washing zone with means (7) for supplying washing liquor to the solution threads directly after stretching and before the formation of the nonwoven, whereby partially coagulated cellulose filaments are formed. The purpose of this first washing step is to remove part of the solvent from the
    To remove filaments, partially coagulate them, thereby making their surface less sticky and thus regulating the degree of union of filaments and fixing the achieved filament stretching. The wash liquor can be sprayed through nozzles
    2o, which are designed and arranged in such a way that they provide essentially continuous spray jet lines on filaments. Depending on the design of the nozzles, the spray jet can produce, for example, aerosol or spray mist. A number of spray nozzles on both sides of the
    Filaments are arranged and have the ability
    Control fleet throughput and droplet size. The arrangement is intended to enable the position and angle of the fleet application to be adjusted. The wash liquor used in this process step can be connected to the wash liquor used downstream or be independent thereof.
    • A nonwoven forming step, which is carried out in a nonwoven forming zone with a nonwoven forming device (4), which could be a screen belt or alternatively a perforated drum, on which the partial
    5/32
    Lenzing AG, PL0591 coagulated filaments are deposited to form a fleece (11), the fleece-forming device (4) having a porosity sufficient to enable the gas stream and washing liquor to be drawn off therethrough, for example by means of a liquid and
    Air removal device (8). For example, the forming device could be a belt or the outer, permeable surface of a drum capable of operating at the required web speed. A key feature of the forming device is efficient io management and removal of extrusion air and excess
    Allow wash liquor from the spray nozzles. The forming device has a permeability sufficient to enable gas flow and wash liquor to be collected and processed through a vacuum system
    Subtract reuse while doing a good filing of the
    To enable filaments for fleece formation. For example, tapes with a permeability of approximately 4000 to 15000 m 3 / m 2 / h at a pressure difference of 100 Pa, for example of 9000 m 3 / m 2 / h at 100 Pa, have been found to be suitable. The suction pressure and the effective one
    Volume flow are determined so that they are the undamaged
    Maintain the integrity of the fleece with the maximized removal of liquid and sufficient fixation of the filaments on the belt. The education zone can also be equipped with one or more washing modules, which in the next
    Section is described. The combination of
    Spinning solution throughput per opening, filament drawing conditions and
    Forming device speed controls the fleece weight and filament fineness.
    · A second washing step, which is carried out in a second washing zone with a
    Washing device (5), which comprises a plurality of modular washing modules (2), is carried out, each washing module (2) having a means (9) for applying washing liquor to the fleece (11) in such a way that the fleece structure and the very fragile coagulate Filaments not
    6/32 • · • · · · ·· · · · ·
    Lenzing AG, PL0591, especially during the first washing steps, and a dewatering device (10) for at least partially dewatering the fleece (11), for example by vacuum suction. The fleece of the
    Education device transported. It could be part of the formation zone (e.g. a single belt or drum) or a separate device (e.g. a separate belt or drum). The washing device itself could be a single device (e.g. a belt or a drum) io or for example a plurality of belts or drums. It is operated at the same production speed as the forming device and is equipped with several washing modules. The number of washing modules can be varied to achieve the desired washing efficiency for the product being produced. each
    Washing module consists of a means for uniformly applying washing liquor (uniform means with up to 5% variability tolerance of the flow of the washing liquor) to the fleece as a liquor curtain over the entire width of the fleece at a controlled rate and temperature and with a sufficiently low force to apply the fleece or not to damage individual filaments. This can be done via a fleet feed box consisting of two chambers separated by a grid to compensate for the pressure drop and an outlet slot. Everything can be adjusted to meet the fleet flow requirements. For every washing module there is everyone
    Washing liquor application device a dewatering device (for example vacuum suction) and one
    Washer liquor collection device assigned. The used washing liquor can then be taken from the collection facility to
    Reuse or solvent recovery can be transported. The dewatering device is positioned at a distance downstream of the wash liquor application device which is sufficient to allow an adequate dwell time for the wash liquor to act. Usually the wash zone is in counterflow mode
    7/32 • · · »·· • ·«
    Lenzing AG, PL0591, wherein the amine oxide concentration increases as the wash liquor is pumped upstream while it is used to wash the nonwoven.
    • A means (6) for collecting the washed fleece (11) or
    Transfer of the fleece (11) directly to further processing stages.
    • The process can be operated at line production speeds of the nonwoven (11) formed from 5 m / min to 1000 m / min. In a preferred embodiment of this invention, line production speeds can range from 25 to 500 m / min.
    io · The washing liquor is water, a mixture of water and amine oxide or another liquid suitable for removing solvents. In particular, wash liquor, which could be pure water, a mixture of water and amine oxide, or another liquid suitable for removing amine oxide from filaments. For example, fresh demineralized wash liquor could be found in the wash zone
    Water that is introduced at the last washing stage and pumped countercurrently from each fleet collection stage
    Wash upstream devices. This used wash liquor can then either
    Recovery for reuse in the manufacture of the
    Spinning solution are transported or used as part of the feed material for spraying filaments in the formation zone before the nonwoven formation and then passed for recovery. The wash liquor temperatures can range from 5 - 85 ° C.
    Optionally, the device for concentrating washing liquor by recirculation at one or more washing stations can be provided.
    Line production speeds of the nonwoven (11) formed of about 5 m / min will be feasible for producing thick nonwoven with a thickness of up to 100 mm. High line production speeds will be possible for thin nonwovens.
    8/32 • · 4 t • · · · · • · · · • · · »• · · · • · ·« • · · · * · ·· • · · · · • · · · • · · · · • · · ···· «··
    Lenzing AG, PL0591
    In a preferred embodiment of the invention, the washing liquor (7) in the first washing step before the nonwoven formation is in a form such as, for example, as a continuous spray jet line, curtain, aerosol or mist, inter alia through nozzles, slots, rotating pressure rollers or rotating disks, which the washing liquor is in Throw the solution threads onto the solution threads. Other means that serve the same purpose will work for this invention.
    In a further preferred embodiment of the invention, the washing liquor (7) used in the first washing step is either the used washing liquor which comes from the first washing module (2) in the second washing zone (5) or becomes independent of the washing liquor in the second washing zone fed.
    In particular, the forming device (4) can be a sieve belt or a perforated drum, the permeability of the forming device (4) being selected such that it allows the gas stream and washing liquor to pass through, and thereby good web formation, preferably 4000 and 15000 m 3 / m 2 / h at a pressure difference of 100 Pa.
    According to the method of the invention, the second washing device (5) can be operated in countercurrent mode, with fresh washing liquor being added to the most downstream washing module (2).
    According to the method of the invention, in each washing module (2) the washing liquor application device (9) applies the washing liquor as a uniform, closed liquor curtain over the entire width of the fleece (11) at a controlled rate and temperature. The application device (9) in particular should not supply the wash liquor as individual jets, since these
    Radiation could damage the fleece structure and the very fragile coagulated filaments, especially during the first washing steps. Washing liquor mist or the like will also not fulfill the purpose of this invention.
    9/32 • · · ·
    Lenzing AG, PL0591
    In a particularly preferred embodiment of the invention, in each washing module (2) the dewatering device (10) is positioned at a distance downstream of the washing liquor application device (9) which is sufficient to enable an adequate dwell time per washing module so that the
    Wash liquor can work.
    It was recognized that the method according to the invention can be operated in a very economical manner if the adequate dwell time per washing module is 0.06 to 120 seconds, preferably 0.12 to 12 10 seconds, in particular 0.24 to 6 seconds. Surprisingly, it was recognized that this simple teaching made it possible to find an optimum between the number of washing modules (2) and the total length of the washing line (i.e. the total length of the washing device (5), which consists of all washing modules (2)). Both a higher number of
    Washing modules as well as a longer car wash length would increase investment costs, and operating more washing modules would increase operating costs due to an increased need for wash liquor and energy for pumps and vacuum.
    As explained above, an essential requirement of the method is a good coordination between the number of washing modules and the total length of the washing zone. Surprisingly, it was recognized that an optimum of the aforementioned requirements can be determined by changing the dwell time of the newly invented washing modules in the washing zone in accordance with the time ranges just mentioned above, which results in a reduction in the washing zone length overall. By applying this teaching, the total residence time in a washing zone for the
    High-speed production of nonwovens reduced by at least 10%, with an amine oxide concentration of 25% in the last washing module.
    In addition, the number and separation of washing modules in the washing zone can be changed in order to optimize the washing efficiency for each product type (e.g. different fleece thicknesses).
    10/32 • · · · · · • · · * · · «· · • · · • ·
    Lenzing AG, PL0591
    It can also be a preferred embodiment of the method according to the invention if all washing modules (2) of the washing device (5) have essentially the same design and the same residence time per washing module. This simplifies the engineering of the washing device (5) and its operation, since no individual differences have to be taken into account. Various washing modules can of course also be used for specific requirements, for example for the production of special products.
    In order to increase the wash liquor solvent concentration, one or more of the wash modules (2) can have means for dispensing wash liquor internally, i.e. to recirculate within this same wash module. In such an operating mode, only a part of the used washing liquor is passed on to the subsequent washing module (2). To be a viable one
    To maintain the economics of the process, it is important that used wash liquor for solvent recovery has an amine oxide concentration of at least 15%, preferably 20%, in particular greater than 25%.
    The method according to the invention can further comprise a method step for adding a finish application and / or inline hydroentangling (3) to the fleece (11). Such process steps are generally well known to those skilled in the art for hydroentangling, as is described, for example, in EP 2 013 390. Optionally, for example, the end of the washing zone can comprise a means for applying finishing agents to the washed fleece.
    The method according to the invention described above can further comprise admixing material to the fleece (11) by dissolving or dispersing the material in the fluid of a hydroentanglement step (3). This material could be, for example, a flame retardant compound, a colorant, a crosslinking agent, a plasticizer, a chitosan or chitosan derivative or the like. Various other modifying substances, for example dyes, antibacterial
    11/32 • *
    Lenzing AG, PL0591
    Products, ion exchange products, activated carbon, nanoparticles, lotions, superabsorbents, impregnating agents, finishing agents, grafting agents, binders and mixtures thereof can be added during or under the washing steps in the washing zone or in similar, subsequent process steps. Those skilled in the art are aware of how such materials mentioned above are to be added in which step of the lyocell meltblowing process. This invention is equally applicable to the application of solution-based or dispersed chemical treatments
    Solid particles applicable to the cellulose fleece. It is also in the same
    Dimensions applicable to cellulose nonwovens in which the cellulose contains incorporated additives. Other uses for the invention will be apparent to those skilled in the art.
    The method according to the invention can also include means for attaching a
    Layer of a further material, preferably a fiber, film or fleece layer, on the fleece (11) on one or both sides at any point in the process. For example, the nonwoven fabric according to the present invention could be molded directly onto another material that is applied to the formation zone upstream of the point of formation of the nonwoven fabric of the present invention. Nonwovens could also be combined at any point on the wash zone or downstream. The properties of the combined laminate web would be directly influenced by where the first combination with the fleece took place.
    With this embodiment, it is possible to produce composites which, for example, consist of a layer of the cellulose nonwoven produced according to the invention and one or more additional layers on one or both sides of the nonwoven. Sandwich constructions in which the cellulosic fleece between two, optionally different,
    Layers made of, for example, a film or fleece-like material are possible. The layer can essentially consist of a material selected from the group comprising cellulosic materials, for example cellulosic fibers and cellulose, non-cellulosic polymers and mixtures thereof. more details
    12/32 • ·
    Lenzing AG, PL0591 of possible multilayer materials can be found in paragraphs [0031] to [0048] of EP 2 013 390.
    The completely washed nonwoven can then be further processed as required (for example as a roll that has never dried) or can be conveyed directly to a drying stage.
    Comment [hl]: In my opinion, the brackets must be placed here (not as in the original!)
    All systems used are designed in such a way that they enable energy, water vapor and chemicals to be recovered and prevent droplets of washing liquor or other liquids from dripping onto the fleece in an uncontrolled manner. For example, protective hoods are placed over the car wash at suitable angles to ensure that any condensation formed will run to one side of the car wash and not to the nonwoven.
    Another aspect of the invention is a nonwoven product, which consists of essentially endless filaments and can be produced by the method described in this document, with a basis weight between 5 and 250 gsm. Such a product can only be manufactured economically by the process described in this document.
    Another aspect of the invention is an apparatus for making cellulosic nonwovens that are formed directly from Lyocell spinning solution comprising:
    • an extrusion device (1), which is able to extrude several threads of Lyocell solution, which are arranged in particular in one or more rows to form a curtain, and is also able to stretch the solution threads , as described for example in EP 1093536 B1;
    • a first washing zone with means (7) for supplying washing liquor to the solution threads directly after stretching and before
    13/32 · ♦ ···· • ·
    Lenzing AG, PL0591
    Formation of fleece, whereby partially coagulated cellulose filaments are formed;
    • a fleece formation zone with a fleece formation device (4), as already described above, onto which the partially coagulated
    Filaments are deposited to form a fleece (11), the
    Fleece forming device (4) has a porosity sufficient to enable gas flow and washing liquor to be drawn off therethrough, for example by means of a liquid and air removal device (8);
    io · a second washing zone with a washing device (5), which comprises a plurality of modular washing modules (2), wherein • each washing module (2) has a means (9) for applying washing liquor to the fleece (11) in such a way that the fleece structure and the very fragile coagulated filaments (especially during the first
    Washing steps) and not be damaged
    Dewatering device (10) for at least partially dewatering the fleece (11), for example by vacuum suction, and • a means (6) for collecting the washed fleece (11) or for transferring the fleece (11) directly to others
    Processing stages, and • that the device can be operated at line production speeds of the nonwoven (11) formed from 5 m / min (which would be feasible for thick nonwoven with a thickness of up to 100 mm) to 1000 m / min.
    The device according to the invention is preferably designed to be operated at line production speeds of 25 to 500 m / min. The device according to the invention is designed in such a way that it is able to be operated with a washing liquor which is water, a mixture of water and amine oxide or another liquid which is suitable for removing solvent.
    14/32 * ♦ · ♦ · · ·· ··
    Lenzing AG, PL0591
    In a preferred embodiment of the invention, the means for applying the wash liquor (7) to the solution threads prior to the formation of the fleece consist of nozzles, slots, rotating pressure rollers or rotating disks which are able to throw the wash liquor in the direction of the solution threads. Other means that serve the same purpose will work for this invention.
    In particular, the forming device (4) can be a screen belt or a perforated drum, as has already been described above, the permeability of the forming device (4) being selected such that it enables the gas stream and washing liquor to pass through, and thereby good web formation, preferably 4000 and 15000 m 3 / m 2 / h at a pressure difference of 100 Pa.
    In particular, the second washing device (5) is able to
    To be operated in countercurrent mode, with fresh washing liquor being added to the most downstream washing module (2).
    In a preferred embodiment of the invention is in each
    Washing module (2) the washing liquor application device (9) is able to apply the washing liquor as a uniform, closed liquor curtain over the entire width of the fleece (11) at a controlled rate and temperature.
    In a further preferred embodiment of the invention, in each washing module (2) the dewatering device (10) is positioned at a distance downstream of the washing liquor application device (9) which is sufficient to allow an adequate dwell time per washing module so that the washing liquor can work. The adequate dwell time per wash module is
    0.06 to 120 seconds, preferably 0.12 to 12 seconds, in particular
    0.24 to 6 seconds.
    All washing modules (2) of the washing device (5) preferably have essentially the same construction and the same residence time per
    15/32 ·· ···· ··
    Lenzing AG, PL0591
    Wash module on. This simplifies the engineering of the washing device (5) and its operation, since no individual differences have to be taken into account. For specific requirements, for example for the production of special products, different ones can of course also be used
    Washing modules are used.
    In order to increase the wash liquor solvent concentration, one or more of the wash modules (2) may have means for dispensing wash liquor internally, i.e. to recirculate within this same wash module. In such an OK operating mode, only part of the used washing liquor is passed on to the subsequent washing module (2).
    The device according to the invention can further comprise means for adding a finish application and / or inline water jet consolidation (3) to the fleece (11). Such agents are generally well known to those skilled in the art for hydroentangling, as described, for example, in EP 2 013 390.
    The device according to the invention described above can also have means for
    Mixing material to the nonwoven (11) by dissolving or dispersing the material in the fluid of a hydroentanglement step (3). This material could be, for example, a flame retardant compound, a colorant, a crosslinking agent, a plasticizer, a chitosan or chitosan derivative or the like.
    The device according to the invention can further comprise means for attaching a layer of a further material, preferably a fiber, film or nonwoven layer, to the nonwoven (11) on one or both sides.
    The invention will now be illustrated by means of examples. These examples in no way limit the scope of the invention. The invention also encompasses any other embodiments which are based on the same inventive concept.
    16/32 • · · • · · • · · ··
    Lenzing AG, PL0591
    Examples 1 to 12
    To make a cellulosic nonwoven with a basis weight of 15 gsm and an average filament size of 1.0 dtex, Lyocell spinning solution, which contains 13% cellulose, is made from one arrangement
    Meltblown spinning beams, as described in EP 1093536 B1, extruded vertically downwards with an equivalent throughput of 200 kg / h of cellulose per meter of fleece width. The current and temperature of the meltblown air supply are adjusted to achieve the required filament drawing. The drawn filaments are then subjected to a first washing step: demineralized water at 30 ° C. is sprayed onto each long edge of the filament curtain by individual spray bars. Each bar contains spray nozzles which are arranged such that they feed a continuous line of aerosol droplets onto the filaments, as is described in EP 1093536 B1. The partially coagulated
    Filaments are then placed on the in the subsequent formation step
    Forming device filed, which contains a horizontal porous conveyor belt that moves at 476 m / min. A vacuum system is operated under the belt to ensure even filament deposition, to maintain a uniform web thickness and to remove excess extrusion air and liquor from the spray nozzles. The belt permeability is 9000 m7m7h, and the vacuum system creates a pressure difference of 100 Pa across the belt. Air and wash liquor are separated. Used washing liquor becomes one
    Solvent recovery unit for reuse in the manufacture of
    Spinning solution supplied The fleece is transported on the belt to the washing zone, which is arranged as a later part of the same horizontal porous conveyor belt and consists of a series of washing modules, each of which wash liquor is applied to the fleece as a 'curtain'. The washing liquor is then removed through the belt using a vacuum system.
    Washing modules are separated to ensure a sufficient dwell time for good washing efficiency. Washing liquor, which consists of demineralized water at 60 ° C., is introduced at the last washing module and, in countercurrent operation, is gradually pumped upstream through each of the other washing modules. The total consumption of demineralized
    17/32
    Lenzing AG, PL0591
    Water (in education zone spray jets and washing zone) is approximately 6 m7h per meter of fleece width. Used washing liquor is transferred for reuse in the manufacture of a spinning solution for solvent recovery. The wet fleece is at the end of the
    Washer collected and then dried offline using a cylinder dryer. Twelve different wash zone settings were tested, the length and dwell time of the individual wash modules and the number of modules being changed as listed in Table 1. All washing modules were of the same type.
    Table 1: Plant design results
    example dwellmodule numbermodules wash roadoverall length dwelltotal linearreduction reductiontheamount ofwashingmodules (S) (N) (M) (S) (%) (%) 1 0.44 41 143.5 18.1 0 0 2 0.63 25 125 15.8 13 39 3 0.82 19 123.5 15.6 14 54 4 1.01 15 120 15.1 16 63 5 1.20 13 123.5 15.6 14 68 6 1.39 11 121 15.2 16 73 7 1.58 10 125 15.8 13 76 8th 1.76 9 126 15.9 12 78 9 1.95 8th 124 15.6 14 80 10 2.14 8th 136 17.1 5 80 11 2.33 7 129.5 16.3 10 83 12 2.52 7 140 17.6 2 83
    Surprisingly, it emerged from these experiments that for the same line speed, i.e. same capacity, car wash length and
    Product quality can be reduced by 2 to 16% and the number of washing modules by 39 to 83%.
    18/32 ··
    Lenzing AG, PL0591
    权利要求:
    Claims (25)
    [1]
    1. A method of making cellulosic nonwovens that are formed directly from Lyocell spinning solution comprising:
    a. an extrusion step which uses an extrusion device (1) which is capable of extruding and also capable of extruding several threads of Lyocell solution, which are arranged in particular in one or more rows to form a curtain, to stretch the threads,
    b. a first washing step, which is carried out in a first washing zone with means (7) for supplying washing liquor to the solution threads directly after the stretching and before the formation of the fleece, as a result of which coagulation occurs in part
    Cellulose filaments are formed
    c. a nonwoven forming step carried out in a nonwoven forming zone with a nonwoven forming device (4) on which the partially coagulated filaments are deposited to form a nonwoven (11), the nonwoven forming device (4) having a porosity sufficient to enable To draw off gas flow and wash liquor through them,
    d. a second washing step, which is carried out in a second washing zone with a washing device (5) which comprises a plurality of modular washing modules (2), wherein
    e. each washing module (2) means (9) for applying washing liquor to the fleece (11) in such a way that the fleece structure and the coagulated filaments are not damaged, and a dewatering device (10) for at least partially dewatering the fleece (11) includes, and
    f. a means (6) for collecting the washed fleece (11) or transferring the fleece (11) directly to further processing stages, and
    [2]
    2. The method according to claim 1, wherein the washing liquor (7) which on the
    Solution threads are applied before the nonwoven formation, in a form such as io, for example, as a continuous spray line, curtain, aerosol or mist, among other things by nozzles, slots, rotating pressure rollers or rotating disks, which spin the washing liquor in the direction of the solution threads.
    15
    [3]
    3. The method according to claim 1, wherein the washing liquor (7) used in the first washing step is either the used washing liquor coming from the first washing module (2) in the second washing zone (5) or independently of the washing liquor in the second Washing zone is fed.
    [4]
    4. The method of claim 1, wherein a permeability of the formation device (4) is selected to allow the passage of gas flow and washing liquor and thereby a good nonwoven formation, preferably between 4000 and 15000 m 3 / m 2 / h
    25 to allow a pressure difference of 100 Pa.
    [5]
    5 23. The apparatus of claim 15, wherein one or more of the
    Washing modules (2) has means for internally recirculating wash liquor in order to increase the wash liquor solvent concentration.
    5 are able to spin the wash liquor in the direction of the solution threads exist.
    5 drainage device (10) at a distance downstream of the
    Washing liquor application device (9) is arranged, which is sufficient to allow an adequate residence time per washing module so that the washing liquor can act.
    io
    5. The method according to claim 1, wherein the second washing device (5) is operated in countercurrent operation, wherein fresh washing liquor is added to the most downstream washing module (2)
    Turns 30.
    5 is amine oxide or another liquid suitable for removing solvent
    [6]
    6. The method according to claim 1, wherein in each washing module (2) the wash liquor application device (9) the wash liquor as a uniform,
    [7]
    7. The method according to claim 1, wherein in each washing module (2)
    [8]
    8. The method according to claim 7, wherein the adequate residence time per washing module is 0.06 to 120 seconds, preferably 0.12 to 12 seconds, in particular 0.24 to 6 seconds.
    [9]
    9. The method according to claim 7, wherein all washing modules (2) of the
    [10]
    10. The method of claim 1, wherein one or more of the washing modules (2) have the ability to wash liquor internally
    Recycle 2o to increase the wash liquor solvent concentration.
    [11]
    11. The method according to claims 1-10, further comprising a method step for adding a finish application and / or an inline hydroentangling (3) to the nonwoven (11).
    [12]
    12. The method according to claim 1-10, wherein the fleece (11) material is mixed by dissolving or dispersing the material in the fluid of a hydroentanglement step (3).
    30
    [13]
    13. The method according to claim 1-12 in combination with the attachment of a layer of a further material, preferably a fiber, film or nonwoven layer, to the nonwoven (11) on one or both sides.
    [14]
    14. Product that can be produced by the method according to claims 1-13, with a basis weight between 5 and 250 gsm.
    [15]
    15 disperse the material in the fluid one
    Water jet consolidation step (3).
    26. The apparatus of claim 15-25, further comprising means for attaching a layer of another material, preferably one
    15 is able to be operated in countercurrent mode, fresh wash liquor being added to the most downstream washing module (2).
    15. A device for producing cellulose-based nonwovens which are formed directly from Lyocell spinning solution, comprising:
    a. an extrusion device (1) which is able to extrude a plurality of threads of lyocell solution, which are arranged in particular in one or more rows to form a curtain, and is also able to stretch the solution threads,
    b. a first washing zone with means (7) for supplying washing liquor to the solution threads immediately after stretching and before the formation of the fleece, whereby partially coagulated cellulose filaments are formed;
    c. a nonwoven forming zone with a nonwoven forming device (4) on which the partially coagulated filaments are deposited to form a nonwoven (11), the nonwoven forming device (4) having a porosity sufficient to allow gas flow and wash liquor therethrough deducted
    d. a second washing zone with a washing device (5) which comprises a plurality of modular washing modules (2), wherein
    e. each washing module (2) means (9) for applying washing liquor to the fleece (11) in such a way that the fleece structure and the coagulated filaments are not damaged, and a dewatering device (10) for at least partially dewatering the fleece (11) includes, and
    f. a means (6) for collecting the washed fleece (11) or for transferring the fleece (11) directly to further processing stages, and
    G. that the device can be operated at line production speeds of the nonwoven (11) formed from 5 m / min to 1000 m / min.
    15 washing device (5) essentially the same type and the same
    Have residence time per wash module.
    [16]
    16. The apparatus of claim 15, wherein the means for applying the washing liquor (7) to the solution threads prior to the formation of fleece from nozzles, slots, rotating pressure rollers or rotating disks
    [17]
    17. The device according to claim 15, wherein the permeability of the formation device (4) is selected such that it enables the gas flow and washing liquor to pass through, and thereby good nonwoven formation, preferably between 4000 and 15000 m7 m 2 / h at a pressure difference of 100 Pa, allows.
    [18]
    18. The apparatus of claim 15, wherein the second washing device (5)
    [19]
    19. The apparatus of claim 15, wherein in each washing module (2)
    19/32 • ·· • ·· · · • · · • · · • · · • ······ ··· ·· • · · • · · • ··· • · • ··
    Lenzing AG, PL0591
    G. that the method can be operated at line production speeds of the nonwoven (11) formed from 5 m / min to 1000 m / min, and
    H. that the wash liquor is water, a mixture of water and
    [20]
    20 fiber, film or fleece layer, on the fleece (11) on one or both
    Pages.
    20. The apparatus of claim 15, wherein in each washing module (2)
    25 drainage device (10) at a distance downstream of the
    Washing liquor application device (9) is arranged, which is sufficient to allow an adequate residence time per washing module so that the washing liquor can act.
    21. The apparatus of claim 20, wherein the adequate residence time per
    Washing module 0.06 to 120 seconds, preferably 0.12 to 12 seconds, in particular 0.24 to 6 seconds.
    20 wash liquor application device (9) is able to apply the wash liquor as a uniform, closed liquor curtain over the entire width of the fleece (11) at a controlled rate and temperature.
    20/32 ·· · · · · · · • · · · • · · * • · · · ·· ·· ·· ···· ·· ··· ··
    Lenzing AG, PL0591 closed fleet curtain across the entire width of the fleece (11) at a controlled rate and temperature.
    [21]
    21/10/2016 22:51
    21/32 ·· ··· • · • · ···
    Lenzing AG, PL0591
    [22]
    22. The apparatus of claim 15, wherein all washing modules (2) of the
    Washing device (5) have essentially the same design and the same residence time per washing module.
    22/32 »« · »· ··· ····
    Lenzing AG, PL0591
    [23]
    23/32 ·· • · • · • · • · ·· ·· • ·· ·· · · • · • · • · ··· «··· ··· ·· • · ··· ··
    Lenzing AG, PL0591
    [24]
    24/32 £ 1-um -önb bcubb from: i_Hia rHitNiwtbtiN-'wiBi +40 rbfc: roi bb4b
    Hn: + 4O 1 O4SO
    b.bH'b ^
    Lenzing AG, PL0591 ·· ·· ·· * · # · • ··· ···· ·· ·· • · · · • ·· · ;; :: ::
    · * ·· ·· ··
    Fig u re 1
    IO
    ΙΛ «T
    24. The apparatus of claims 15-23, further comprising means for io adding a finish application and / or inline hydroentangling (3) to the nonwoven (11).
    25. The apparatus of claims 15-24, further comprising means for admixing material to the nonwoven (11) by dissolving or
    [25]
    25/32
    No .: R382 L1
    P.024 / 024
    类似技术:
    公开号 | 公开日 | 专利标题
    AT519489B1|2021-11-15|Method and apparatus for producing cellulose-based nonwovens which are formed directly from Lyocell spinning solution
    DE1760662C3|1975-10-02|Process for the continuous production of nonwovens from pdyamide-containing threads
    AT406386B|2000-04-25|METHOD AND DEVICE FOR PRODUCING CELLULOSIC MOLDED BODIES
    EP1936017A1|2008-06-25|Method and device for manufacturing a spunbonding fabric made of cellulose filaments
    EP2128320B1|2013-09-25|Method and device for the manufacture of nonwoven material from filaments
    EP1883721A1|2008-02-06|Method and device for cutting spun threads containing nmmo and for stacks of cellulose fibres
    DE60303028T2|2006-08-24|DEVICE AND METHOD FOR THE PRODUCTION OF FIBER TONES
    DE2532900A1|1976-02-05|METHOD FOR PRODUCING SPINNED FIBERS
    WO2005080661A1|2005-09-01|Method for the production of non-wovens, non-wovens, and use thereof
    EP1402100A1|2004-03-31|Method and device for treating a fiber mass
    DE1757611A1|1971-12-23|Process for the production of spunbonded nonwovens and filter rods made from them
    DE69822127T2|2005-02-03|Improvements to making nonwovens with an electrostatic charged conveyor
    EP3199671B1|2020-03-04|Device for manufacturing non-woven material
    WO2021170609A1|2021-09-02|Method for producing spunbonded fabric
    WO2021122379A1|2021-06-24|Method for producing a spunbond nonwoven
    WO2021122378A1|2021-06-24|Method for producing spunbonded fabric
    DE102020100472A1|2021-07-15|Method for producing a composite nonwoven web and apparatus for producing a composite nonwoven web
    WO2021170607A1|2021-09-02|Method and device for producing spunbonded fabric
    WO2021170608A1|2021-09-02|Method and device for producing spunbonded fabric
    WO2021122377A1|2021-06-24|Method for producing a spunbond nonwoven
    DE102018118884A1|2020-02-06|Device for dewatering a wet-laid nonwoven web
    EP3239397B1|2019-06-12|Method and assembly for producing a flat impregnated fibre product
    WO2007023003A1|2007-03-01|Multiple spinning nozzle arrangement and method for suctioning and blowing
    WO2020234122A1|2020-11-26|Method and device for cleaning spinnerets while producing cellulose spunbonded nonwoven fabric
    DE102004024065A1|2005-12-08|Process for producing continuous moldings and spinning head
    同族专利:
    公开号 | 公开日
    EP3529405B1|2021-12-08|
    KR20190066064A|2019-06-12|
    AT519489B1|2021-11-15|
    CA3040192A1|2018-04-26|
    TW201823534A|2018-07-01|
    JP2019532194A|2019-11-07|
    RU2019111062A|2020-11-23|
    EP3529405A1|2019-08-28|
    RU2757398C2|2021-10-15|
    RU2019111062A3|2021-03-10|
    CN109844202A|2019-06-04|
    WO2018071928A1|2018-04-26|
    BR112019006952A2|2019-07-02|
    US20190264356A1|2019-08-29|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    AT413285B|2003-11-06|2006-01-15|Chemiefaser Lenzing Ag|Washing of absorbent material, e.g. lyocell fiber tow, involves several stages in contra-flow with appreciable amounts of absorbed liquid carried to next stage|
    WO2006035458A1|2004-09-17|2006-04-06|Birla Research Institute For Applied Sciences|A process for preparing a non-woven cellulosic structure and the non-woven cellulosic structure prepared therefrom|
    AT503625B1|2006-04-28|2013-10-15|Chemiefaser Lenzing Ag|WATER-IRRADIZED PRODUCT CONTAINING CELLULASIC FIBERS|
    AT505621A4|2007-11-07|2009-03-15|Chemiefaser Lenzing Ag|METHODS FOR PRODUCING A WATER-IRRADIZED PRODUCT CONTAINING CELLULOSIC FIBERS|
    GB9412500D0|1994-06-22|1994-08-10|Courtaulds Fibres Holdings Ltd|Fibre manufacture|
    FR2735794B1|1995-06-26|1997-09-19|Elysees Balzac Financiere|PROCESS FOR THE PREPARATION OF A MIXTURE OF CELLULOSIC FIBERS AND MICROFIBERS|
    GB9611252D0|1996-05-30|1996-07-31|Courtaulds Fibres Holdings Ltd|Fibre manufacture|
    US6210801B1|1996-08-23|2001-04-03|Weyerhaeuser Company|Lyocell fibers, and compositions for making same|
    CA2264180C|1996-08-23|2009-09-01|Mengkui Luo|Lyocell fibers and process for their preparation|
    US6022447A|1996-08-30|2000-02-08|Kimberly-Clark Corp.|Process for treating a fibrous material and article thereof|
    GB9625634D0|1996-12-10|1997-01-29|Courtaulds Fibres Holdings Ltd|Method of manufacture of nonwoven fabric|
    GB2337957A|1998-06-05|1999-12-08|Courtaulds Fibres|Method of manufacture of a nonwoven fabric|
    AT406588B|1998-09-29|2000-06-26|Chemiefaser Lenzing Ag|METHOD FOR PRODUCING CELLULOSIC FIBERS|
    DE10065859B4|2000-12-22|2006-08-24|Gerking, Lüder, Dr.-Ing.|Method and apparatus for producing substantially endless fine threads|
    US20040207110A1|2003-04-16|2004-10-21|Mengkui Luo|Shaped article from unbleached pulp and the process|
    US20050056956A1|2003-09-16|2005-03-17|Biax Fiberfilm Corporation|Process for forming micro-fiber cellulosic nonwoven webs from a cellulose solution by melt blown technology and the products made thereby|
    WO2005106085A1|2004-04-26|2005-11-10|Biax Fiberfilm Corporation|Apparatus , product and process forming micro-fiber cellulosic nonwoven webs|
    CN102317515B|2007-08-31|2015-06-10|可隆工业株式会社|Preparation method for lyocell filament fibers, lyocell filament fibers, tire cord, and preparation method for tire cord|TW202006199A|2018-07-17|2020-02-01|奧地利商蘭仁股份有限公司|A method and device for the separation of solvent from process air in the production of spundbond fabrics|
    TW202031950A|2018-12-05|2020-09-01|奧地利商蘭仁股份有限公司|Method for solvent and cellulose recycling in the manufacture of cellulosic spunbonded nonwovens|
    EP3828320A1|2019-11-26|2021-06-02|Lenzing Aktiengesellschaft|Countercurrent washing|
    WO2021122379A1|2019-12-17|2021-06-24|Lenzing Aktiengesellschaft|Method for producing a spunbond nonwoven|
    WO2021122378A1|2019-12-17|2021-06-24|Lenzing Aktiengesellschaft|Method for producing spunbonded fabric|
    TW202136602A|2020-02-24|2021-10-01|奧地利商蘭仁股份有限公司|Process and device for the production of spunbonded nonwoven|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA490/2016A|AT519489B1|2016-10-21|2016-10-21|Method and apparatus for producing cellulose-based nonwovens which are formed directly from Lyocell spinning solution|ATA490/2016A| AT519489B1|2016-10-21|2016-10-21|Method and apparatus for producing cellulose-based nonwovens which are formed directly from Lyocell spinning solution|
    TW106134883A| TW201823534A|2016-10-21|2017-10-12|Process and device for the formation of directly formed cellulosic webs|
    CA3040192A| CA3040192A1|2016-10-21|2017-10-18|Process and device for the formation of directly-formed cellulosic webs|
    RU2019111062A| RU2757398C2|2016-10-21|2017-10-18|Method and device for forming cellulose canvas by direct molding|
    PCT/AT2017/000071| WO2018071928A1|2016-10-21|2017-10-18|Process and device for the formation of directly-formed cellulosic webs|
    US16/342,848| US20190264356A1|2016-10-21|2017-10-18|Process and device for the formation of directly-formed cellulosic webs|
    KR1020197014427A| KR20190066064A|2016-10-21|2017-10-18|Method and apparatus for the formation of directly formed cellulosic webs|
    BR112019006952A| BR112019006952A2|2016-10-21|2017-10-18|process and device for forming directly formed cellulosic networks|
    EP17800357.0A| EP3529405B1|2016-10-21|2017-10-18|Process and device for the formation of directly-formed cellulosic webs|
    JP2019521440A| JP2019532194A|2016-10-21|2017-10-18|Method and apparatus for forming directly formed cellulosic webs|
    CN201780064390.0A| CN109844202A|2016-10-21|2017-10-18|It is used to form the process and equipment of the cellulose mesh directly formed|
    [返回顶部]